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A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.

The aggressive reduction of future diesel engine NOx emission limits forces the heavy- and light-duty diesel engine manufacturers to develop means to comply with stringent legislation. As a result, different exhaust emission control technologies applicable to NOx have been the subject of many investigations. One of these systems is the NOx adsorber catalyst, which has shown high NOx conversion rates during previous investigations with acceptable fuel consumption penalties. In addition, the NOx adsorber catalyst does not require a secondary on-board reductant. However, the NOx adsorber catalyst also represents the most sulfur sensitive emissions control device currently under investigation for advanced NOx control. To remove the sulfur introduced into the system through the diesel fuel and stored on the catalyst sites during operation, specific regeneration strategies and boundary conditions were investigated and developed.

Mass transfer limitations from the bulk gas phase to the surface of the catalyst as well as mass transfer limitations within the washcoat itself have important effects on conversion in washcoated monolith catalysts. These factors depend upon the shape of the channel as well as the loading of washcoat material. This paper outlines a method to describe the washcoat distribution profile for different channel shapes and washcoat loadings. This allows for prediction of effectiveness factors and bulk mass transfer coefficients as a function of cell geometry and washcoat loading for the oxidation of propane. It was found that differences in the diffusion limitations within the washcoat control conversion in the catalyst more than differences in bulk mass transfer rates when comparing different cell shapes. The results show that optimum washcoat loadings exist for the geometry of each cell, and that these optimum loadings are a function of catalyst temperature.

A compact in-situ tensile stress fixture was designed for the study of the combined effects of stress and automotive environments on structural glass fiber-reinforced composite materials. With this fixture, a standardized 300 hour laboratory screening test was developed to compare the residual property loss of composite materials due to concurrent exposure to stress and environment. It is of great importance that the data gathered in the laboratory have correlation to on-vehicle (in-service) performance, and that both lab and real world data be taken with a test system (in-situ test fixtures) capable of providing accurate and consistent results under either test condition.

Gear whine in 1st gear for an automatic transmission that has been in production for nearly thirty years was identified as an NVH issue. Due to advances in vehicle level refinement, and reduction of other masking noises, the automatic transmission gear whine became an issue with the customer. Since the transmission was already in production, the improvements had to be within the boundaries of manufacturing feasibility with existing equipment to avoid costly and time consuming investment in new machines. The approach used was one of identifying optimum values of existing gear parameters to provide a reduction in passenger compartment noise. The problem was in a light truck application. Objective noise measurements were recorded for 10 transmissions from more than 50 driven in vehicles. The transmissions were disassembled and the gears inspected.

The paper outlines and discusses the possibilities of a new instrumentation tool for the analysis of engine and gearbox noise radiation and the prediction of pass-by noise from powertrain test cell measurements. Based on a 32 channel data acquisition board, the system is intended to be quick and easy to apply in order to support engineers during their daily work in the test cell. The pass-by prediction is a purely experimental approach with test cell recordings being weighted by measured transfer functions (from the powertrain compartment to the pass-by point).

A simulated diesel exhaust is treated with a nonthermal plasma discharge under steady state conditions. The plasma effluent is then passed through a sodium zeolite-Y (NaY) catalyst followed by a platinum oxidation catalyst. Detailed FTIR measurements of gas composition are taken before, between, and after the treatment stages. The plasma discharge causes oxidation of NO primarily to NO2, with methyl nitrate and nitric acid byproducts. At the same time, HC is partially oxidized, creating species such as formaldehyde, acetaldehyde, CO and other partial oxidation products. When this mixture passes over the NaY catalyst, part of the NOx is reduced to N2, with the remainder primarily in the form of NO. Methyl nitrate decomposes to form methanol and NOx, and nitric acid is consumed. There is little HC conversion on this catalyst. Small quantities of HCN and N2O are formed. When the mixture then passes over the platinum catalyst, further NOx conversion occurs.

The catalytic activity of selected materials (BaY and NaY zeolites, and γ-alumina) for selective NOx reduction in combination with a non-thermal plasma was investigated. Our studies suggest that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, all materials that are active in plasma-assisted catalysis were found to be very effective for the thermal reduction of NOx in the presence of aldehydes. For example, the thermal catalytic activity of a BaY zeolite with aldehydes gives 80-90% NOx removal at 250°C with 200ppm NOx at the inlet and a VHSV=12,000 h-1. The hydrocarbon reductants, n-octane and 1-propyl alcohol, have also shown high thermal catalytic activity for NOx removal over BaY, NaY and γ-alumina.

We present here a phenomenological analysis of a cascade of two-step discharge-catalyst reactors. That is, each step of the cascade consists of a discharge reactor in series with a catalyst bed. These reactors are intended for use in the reduction of tailpipe emission of NOx from diesel engines. The discharge oxidizes NO to NO2, and partially oxidizes HC. The NO2 then reacts on the catalyst bed with hydrocarbons and partially oxidized HCs and is reduced to N2. The cascade may be essential because the best catalysts for this purpose that we have also convert significant fractions of the NO2 back to NO. As we show, reprocessing the gas may not only be necessary, but may also result in energy savings and increased device reliability.

Meeting upcoming stringent emission standards will require that exhaust gas catalyst systems become active very quickly, function at very high efficiencies and maintain those capabilities at high mileages. This means that contamination of the catalysts by engine oil derived poisons must be minimized. Phosphorus compounds, derived from the zinc dialkyldithio-phosphate (ZDTP) additives that provide antiwear and antioxidant activity, are a principal contaminant that can increase catalyst light off times and reduce catalyst efficiency. Therefore, reducing the concentration of, or eliminating, phosphorus in engine oils is desirable. Doing so, however, requires that oils be reformulated to ensure that wear protection will not be compromised and that oxidation stability will be maintained. To address these concerns, laboratory tests for evaluating oil oxidation and wear performance have been developed and used to evaluate developmental low phosphorus oils.

In the near future the effort on the development of exhaust gas treatment systems must be increased to meet the stringent emission requirements. If the relevant physical and chemical models are available, the numerical simulation is an important tool for the design of these systems. This work presents a CFD model that allows to cover the full range of applications in this area. After a detailed presentation of the theoretical background and the modeling strategies results for the simulation of a close-coupled catalyst are shown. The presented model is also applied to the oxidation of nitrogen oxides, to a diesel particle filter and a fuel-cell reformer catalyst.

In recent years several new gasoline engine technologies were introduced in order to reduce fuel consumption. Controlled autoignition seems to be an alternative to stratified part load operation, which is handicapped due to it's lean aftertreatment system for world wide application. The principal advantages of controlled auto ignition combustion under steady state operation - combining fuel economy benefits similar to stratified charge systems with nearly negligible NOx and soot emissions - are already well known. With the newly developed AVL- CSI system (Compression and Spark Ignition), a precise combustion control is achieved even under transient operation. For compensation of production and operation tolerances a cost optimized cylinder individual control was developed. Completely new functionalities of the engine management system are applied. This lean GDI concept complies with future emission standards without DeNOx catalyst and can be applied worldwide.

Presented in this paper is an on-line method for estimating the oxygen storage capacity contained within a catalyst. The oxygen storage capacity of a catalyst changes over time due to catalyst brick temperatures, poisoned catalyst sites, and thermal aging. Information regarding the current oxygen storage capacity of a catalyst is advantageous in the development of robust emission control strategies and on-board diagnostics. The method of collecting the oxygen storage capacity information is extremely important for measurement accuracy and repeatability. Furthermore, the information must be obtained in such a way that it is transparent to the operator and may be implemented on-line during normal drive cycles. This on-line method for estimation of oxygen storage capacity of a catalyst has been demonstrated on a Ford F150 platform with an underbody catalyst.

Particulate and manganese mass emissions have been measured as a function of mileage for four Escort and four Explorer vehicles using 1) MMT (Methylcyclopentadienyl Manganese Tricarbonyl) added to the gasoline at 1/32 g Mn/gal and 2) gasoline without MMT. The MMT was used in half of the fleet starting at 5,000 miles. The vehicles were driven on public roads at an average speed of 54 mph to accumulate mileage. This report describes the particulate and manganese emissions, plus emissions of four air toxics at 5,000, 20,000, 55,000, 85,000 and 105,000 miles. Four non-regulated emissions were measured and their average values for vehicles without MMT were 0.6 mg/mi for formaldehyde, 0.7 mg/mi for 1,3-butadiene, 9 mg/mi for benzene and 12 mg/mi for toluene. Corresponding values for MMT-fueled vehicles were between 1.5 and 2.4 times higher.

Measurements of oxygen storage capacity (OSC) and HC conversion efficiency for 17 catalysts were carried out in the laboratory. All catalysts with steady state HC efficiency below 90% were found to have roughly equivalent and very low capacities to store oxygen. However, catalyst oxygen storage capacity was seen to rise sharply with HC conversion efficiency in excess of 90 percent. These results parallel the trends which are observed between rear HEGO/EGO indexes for OBD-II catalyst monitoring and HC conversion efficiency. In addition, temperature programed reduction (TPR) was found to lend insight into the relationship between catalyst OSC and HC conversion efficiency by providing a qualitative understanding of the mechanisms by which OSC deteriorates. TPR profiles showed that most of the usable oxygen storage is derived from surface ceria which is interacted with precious metals.

Local air pollution, noise emissions as well as global CO2 reduction and public pressure drive the need for zero emission transport solutions in urban areas. OEMs are currently developing battery electric vehicles with the focus to provide emission free urban transportation combined with lowest total cost of ownership and consequently a positive business case for the end customers. Thereby the main challenges are electric range, product cost, system weight, vehicle packaging and durability. Hence they are the main drivers in current developments. In this paper AVL describes two of its truck and bus solutions - a modular battery concept as well as a concept for an integrated electric axle. Based on the vehicle requirements concept designs for both systems are presented.

The pneumatic air brake system for heavy commercial trucks is composed by a large number of components, aiming its proper work and compliance with rigorous criteria of vehicular safety. One of those components, present along the whole vehicle, is the air brake tube, ducts which feed valves and reservoirs with compressed air, carrying signals for acting or releasing the brake system. In 2011, due to a lack of butadiene in a global scale, the manufacturing of these tubes was compromised; as this is an important raw material present on the polymer used so far, PA12. This article introduces the methodology of selecting, developing and validating in vehicle an alternative polymer for this application. For this purpose, acceptance criteria have been established through global material specifications, as well as bench tests and vehicular validation requirements.

This article is a new methodology to create a strong and reliable procedure to measure oil level at dealers. Most of time, commercial trucks run full loaded. Engine oil level indication systems are designed to measure oil level at that condition. However commercial trucks are assembled and sold empty and without bodies for trucks. In result of this condition, vehicles with a false indication of low engine oil level are detected at dealers' pre-delivery inspection, resulting in oil addition. This oil addition causes unnecessary costs, since vehicles are produced with maximum oil level. The methodology presented in this study analyzes and treats all variables involved in engine oil level measurements from engine production line until dealers' pre-delivery inspection

A demonstration structure was cast in AM60. The structure, known as the Generic Frame Casting or GFC, was designed specifically to mimic features seen in castings for closure applications. Excised samples were subsequently removed from different areas of the casting and tested under axial loading conditions. Component level tests were also conducted. Comparison of the excised sample results and the component level testing indicated the influence of local properties on the component level deformation. It was shown that varying the casting processing conditions could change the local ductility and yield strength in different areas of casting with the same geometry. Lowering the local ductility decreased the total displacement in a component level test and lowered the amount of energy absorption. Therefore, understanding the processing conditions and their influence on the local properties is important for predicting behavior in a component level test.

The paper gives an overview of the partially extremely complex problem when looking into commonalities and differences of the three main application areas of engines and powertrains - automotive, agricultural tractors, and industrial engines, the last being predominantly but not exclusively focused on construction equipment. The modern “platform” approach has been used in the automotive world to a large extent and the learned experiences may be of interest for the agricultural tractors and/or the construction equipment manufacturers. On the other hand the truck engine engineers and manufacturers will learn more about the special requirements of the tractor and the industrial engines fields, and thus influence concepts and development procedures and also the production of the automotive engines which in many cases serve as the basis for derivate engines.